Showing: 8 from total: 1718 publications
1711.
CERTIFICATION OF BDH THERMOCHEMICAL STANDARD BENZOIC-ACID
PILCHER, G
; BICKERTON, J
; DASILVA, MMDCCR
in JOURNAL OF CHEMICAL THERMODYNAMICS, 1984, ISSN: 0021-9614, Volume: 16,
Note, Indexed in: crossref, scopus, wos
1712.
Standard enthalpies of formation of bis(pentane-2,4-dionato)Cu(II) and of four bis(methyl-substituted heptane-3,5-dionato)Cu(II) complexes: the mean (CuO) bond-dissociation enthalpies
Ribeiro Da Silva, MA
; Ribeiro Da Silva, MD
; Carvalho, AP
; Akello, MJ
; Pilcher, G
in The Journal of Chemical Thermodynamics, 1984, ISSN: 0021-9614, Volume: 16,
Article, Indexed in: crossref
1713.
Enthalpies of combustion of 1,2-dihydroxybenzene and of six alkylsubstituted 1,2-dihydroxybenzenes
Ribeiro Da Silva, MD
; Ribeiro Da Silva, MA
; Pilcher, G
in The Journal of Chemical Thermodynamics, 1984, ISSN: 0021-9614, Volume: 16,
Article, Indexed in: crossref
1714.
ON THE MEASUREMENT OF THE IMPEDANCE OF ITIES - THE NITROBENZENE WATER AND 1,2-DICHLOROETHANE WATER INTERFACES
SILVA, F
; MOURA, C
in JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, ISSN: 1572-6657, Volume: 177,
Note, Indexed in: scopus, wos
1715.
On the measurement of the impedance of ities
Silva, F
; Moura, C
in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1984, ISSN: 0022-0728, Volume: 177,
Article, Indexed in: crossref
1716.
IS GOLD LESS HYDROPHILIC THAN MERCURY?
Silva, F
; Hamelin, A
; Parsons, R
in Extended Abstracts, Meeting - International Society of Electrochemistry, 1983,
Proceedings Paper, Indexed in: scopus
1717.
Phase transformations in adsorbed layers of thiourea and halide ions on mercury
Hills, G
; Silva, F
in Journal of Electroanalytical Chemistry, 1982, ISSN: 0022-0728, Volume: 137,
Article, Indexed in: scopus
1718.
ENTHALPIES OF FORMATION OF HEXAKIS(ISOPROPOXY)-DIMOLYBDENUM AND OCTAKIS-(ISOPROPOXY)-DIMOLYBDENUM AND THE METAL-METAL BOND ENTHALPY CONTRIBUTIONS
CAVELL, KJ
; CONNOR, JA
; PILCHER, G
; DASILVA, MAVR
; DASILVA, MDMC
; SKINNER, HA
; VIRMANI, Y
; ZAFARANIMOATTAR, MT
in JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, ISSN: 0300-9599, Volume: 77,
Article, Indexed in: crossref, scopus, wos
Abstract
Standard enthalpies of formation of crystalline samples at 298.15 K were determined by solution calorimetry (oxidative hydrolysis), for ΔHf ⊖[Mo2(OPri) 6, c] = -(1661.8±9) kJ mol-1 and ΔHf ⊖[Mo2(OPri) 8, c] = -(2292.5±10) kJ mol-1. The dissociation process [Mo2(OPri)8, g] → 2 Mo(OPri)4, g is calculated to be endothermic, ΔH ≈ 184 kJ mol-1. A bond-enthalpy/bond-length curve is tentatively proposed for Mo-Mo bonds. A similar curve for Mo-O bonds is given, to fit the limited thermochemical data available. It is concluded that the Mo=Mo bond in Mo2(OPri)8 contributes ca. 200-230 kJ mol-1 to the binding in this molecule.