Showing: 10 from total: 2477 publications
1901. Comments on "Equilibrium and kinetic studies for the biosorption system of copper(II) ion from aqueous solution using Tectona grandis L.f. leaves powder"
Kumar, KV ; Porkodi, K ; Rocha, F
in JOURNAL OF HAZARDOUS MATERIALS, 2007, ISSN: 0304-3894,  Volume: 146, 
Editorial Material,  Indexed in: crossref, scopus, wos 
Abstract This letter reports the way to solve the Redlich-Peterson isotherm. ln addition the importance of constraints for the Redlich-Peterson isotherm exponent was discussed in detail.

1902. Labtermo: Methodologies for the calculation of the corrected temperature rise in isoperibol calorimetry
Santos, LMNBF ; Silva, MT ; Schroeder, B ; Gomes, L
in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, ISSN: 1388-6150,  Volume: 89, 
Article,  Indexed in: crossref, scopus, wos 
Abstract In isoperibol temperature-rise calorimetry, different approaches can lead to the corrected temperature rise. The description of the methodology, as well as an improvement in the approach to the accurate numerical calculation of the corrected temperature rise in isoperibol calorimetry, based on the comparison between the exponential functional description of the initial and final periods and an independent third order polynomial fitting, is presented. The latter is focused on the strategy of minimizing the result dependency on the definition of the main period of the reaction. Furthermore, the dedicated software application Labtermo is introduced.

1903. Equilibrium, kinetics and mechanism modeling and simulation of basic and acid dyes sorption onto jute fiber carbon: Eosin yellow, malachite green and crystal violet single component systems
Porkodi, K ; Kumar, KV
in JOURNAL OF HAZARDOUS MATERIALS, 2007, ISSN: 0304-3894,  Volume: 143, 
Article,  Indexed in: crossref, scopus, wos 
Abstract Batch experiments were carried out for the sorption of eosin yellow, malachite green and crystal violet onto jute fiber carbon (JFC). The operating variables studied are the initial dye concentration, initial solution pH, adsorbent dosage and contact time. Experimental equilibrium data were fitted to Freundlich, Langmuir and Redlich-Peterson isotherm by non-linear regression method. Langmuir isotherm was found to be the optimum isotherm for eosin yellow/JFC system and Freundlich isotherm was found to be the optimum isotherm for malachite green/JFC and crystal violet/JFC system at equilibrium conditions. The sorption capacities of eosin yellow, malachite green and crystal violet onto JFC according to Langmuir isotherm were found to 31.49 mg/g, 136.58 mg/g, 27.99 mg/g, respectively. A single stage batch adsorber was designed for the adsorption of eosin yellow, malachite green and crystal violet onto JFC based on the optimum isotherm. A pseudo second order kinetic model well represented the kinetic uptake of dyes studied onto JFC. The pseudo second order kinetic model successfully simulated the kinetics of dye uptake process. The dye sorption process involves both surface and pore diffusion with predominance of surface diffusion at earlier stages. A Boyd plot confirms the external mass transfer as the rate limiting step in the dye sorption process. The influence of initial dye concentration on the dye sorption process was represented in the form of dimensionless mass transfer numbers (Sh/Sc-0.33) and was found to be agreeing with the expression: Sh/Sc-0.33 = xC(0)(y). (C) 2006 Published by Elsevier B.V.

1904. Comments on "adsorption of 4-chlorophenol from aqueous solutions by xad-4 resin: Isotherm, kinetic, and thermodynamic analysis"
Kumar, KV ; Porkodi, K
in JOURNAL OF HAZARDOUS MATERIALS, 2007, ISSN: 0304-3894,  Volume: 143, 
Editorial Material,  Indexed in: crossref, scopus, wos 
Abstract This letter reports the importance and advantages of the constraints in the Redlich Peterson isotherm exponent.

1905. Experimental thermochemical study of 6-chloro-2,3-dimethylquinoxaline 1,4-dioxide and DFT evaluation of the N-O bond enthalpies in related haloquinoxalines
Gomes, JRB ; Vieira, MAA ; Stovall, DM ; Acree, WE ; Ribeiro da Silva, MDMC
in BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, ISSN: 0009-2673,  Volume: 80, 
Article,  Indexed in: crossref, scopus, wos 
Abstract The standard molar enthalpy of formation at T = 298.15 K of 6-chloro-2,3-dimethylquinoxaline 1,4-dioxide in the gas-phase was derived using the values of the enthalpies of combustion for the crystalline solid, measured by using totating-bomb combustion calorimetry, and of the enthalpies of sublimation, measured by using Calvet microcalorimetry. This value was used for calibrating the computational procedure employed to estimate the gas-phase enthalpies of formation for the deoxygenated quinoxaline derivatives and also to compute the first, second, and mean (N-O) bond dissociation enthalpies in the gas-phase. The B3LYP/6-311+G(2d,2p) calculations were also extended to the fluorine, bromine, and iodine derivatives and to the isomers with a halogen substituted at position 5. When the halogen atom enters the same position in the quinoxaline ring, it was found that the substituent had almost no influence on the computed (N-O) bond dissociation enthalpies, except for 5-fluoro-2,3-dimethylquinoxaline 1,4-dioxide.

1906. Evaluation of COSMO-RS for the prediction of LLE and VLE of alcohols plus ionic liquids
Freire, MG ; Santos, LMNBF ; Marrucho, IM ; Coutinho, JAP
in FLUID PHASE EQUILIBRIA, 2007, ISSN: 0378-3812,  Volume: 255, 
Article,  Indexed in: crossref, scopus, wos 
Abstract The huge number of possible combinations of binary mixtures of alcohols and ionic liquids (ILs) make the exhaustive measurement of all these systems impracticable requiring the use of a predictive model for their study. In this work, the predictive capability of COSMO-RS, a model based on unimolecular quantum chemistry calculations, was evaluated for the description of the liquid-liquid equilibria and the vapour-liquid equilibria of binary mixtures of alcohols and several imidazolium and pyridinium-based ILs. The effect of the ions and alcohols conformers on the quality of the predictions was assessed and the quantum chemical COSMO calculation at the BP/TZVP level derived from the lower energy conformations was adopted. Although a degradation in the liquid-liquid equilibria predictions with increasing size length of the alkyl chain of the alcohol or of the ionic liquid and with the short chain alcohol methanol in the vapour-liquid equilibria predictions were observed, in general a reasonable qualitative agreement between the model predictions and experimental data for a large combination of structural variations of both alcohols and ILs was obtained. COSMO-RS can thus be very useful in the scanning of the growing number of known ILs to find suitable candidates, or help designing new ILs, for specific applications before extensive experimental measurements.

1907. An overview of the mutual solubilities of water-imidazolium-based ionic liquids systems
Freire, MG ; Santos, LMNBF ; Fernandes, AM ; Coutinho, JAP ; Marrucho, IM
in FLUID PHASE EQUILIBRIA, 2007, ISSN: 0378-3812,  Volume: 261, 
Article,  Indexed in: crossref, scopus, wos 
Abstract Ionic liquids (ILs) are a novel class of chemical compounds with interesting properties that are driving a lot of research in several fields. For ionic liquids to be effectively used as solvents in liquid-liquid extractions, the knowledge of the mutual solubilities between ILs and the second liquid phase is fundamental. Furthermore, while ILs cannot volatilise and lead to air pollution, even the most hydrophobic ones present some miscibility with water posturing secondary aquatic environmental risks. Despite the importance of the ILs and water systems, there are few extensive reports on their phase equilibria. The aim of this work is to discuss and understand the mutual solubilities of water and imidazolium-based ILs. The results indicate that these mutual solubilities are primarily defined by the anion followed by the cation alkyl side chain length. It was also found that the solubility of the studied ILs in water is more dependent on the ILs structural modifications than the solubility of water in those ILs. The substitution of the most acidic hydrogen in the imidazolium cation by a methyl group leads to different behaviours in both rich-phases, where the solubility of water in ILs showed to be more hydrogen bonding dependent. From the solubility results it can be concluded that the hydrophobicity of the anions increases in the order [BF4](-) < [CH3(C2H4O)(2)SO4](-) < [C(CN)(3)](-) < [PF6](-) < [N(SO2CF3)(2)](-) while the hydrophobicity of the cations increases, as expected, with the alkyl chain length increase.

1908. Comments on "Removal of lead from aqueous solution using Syzygium cumini L.: Equilibrium and kinetic studies"
Kumar, KV ; Porkodi, K ; Rocha, F
in JOURNAL OF HAZARDOUS MATERIALS, 2007, ISSN: 0304-3894,  Volume: 147, 
Editorial Material,  Indexed in: crossref, scopus, wos 
Abstract This letter reports the importance and advantages of the constraints in the Redlich-Peterson isotherm exponent. (C) 2007 Published by Elsevier B.V..

1909. Batch adsorber design for different solution volume/adsorbent mass ratios using the experimental equilibrium data with fixed solution volume/adsorbent mass ratio of malachite green onto orange peel
Kumar, KV ; Porkodi, K
in Dyes and Pigments, 2007, ISSN: 0143-7208,  Volume: 74, 
Article,  Indexed in: crossref 

1910. Constrain in solving Langmuir–Hinshelwood kinetic expression for the photocatalytic degradation of Auramine O aqueous solutions by ZnO catalyst
VASANTHKUMAR, K ; PORKODI, K ; SELVAGANAPATHI, A
in Dyes and Pigments, 2007, ISSN: 0143-7208,  Volume: 75, 
Article,  Indexed in: crossref